INFINITE-DILUTION ACTIVITY-COEFFICIENTS BY COMPARATIVE EBULLIOMETRY - MEASUREMENTS AND GROUP-CONTRIBUTION CALCULATIONS FOR SOME BINARY-MIXTURES ETHER PLUS N-ALKANE AND ETHER PLUS ALCOHOL

被引:17
作者
DELCROS, S [1 ]
GROLIER, JPE [1 ]
DOHNAL, V [1 ]
FENCLOVA, D [1 ]
机构
[1] PRAGUE INST CHEM TECHNOL,DEPT PHYS CHEM,CR-16628 PRAGUE,CZECH REPUBLIC
关键词
D O I
10.1016/0009-2509(95)00137-T
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
Infinite-dilution activity coefficients gamma(i)(infinity) were measured for 33 solute-solvent pairs of the type ether + n-alkane and ether + alcohol using the comparative ebulliometry technique. The experimental results were compared with the values obtained by two group contribution models, DISQUAC and modified UNIFAC (Dortmund).
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页码:2957 / 2962
页数:6
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