PHOSPHINE-BORANE COMPLEXES - DIRECT USE IN ASYMMETRIC CATALYSIS

被引：154

作者：

BRISSET, H ^{[1
]}

GOURDEL, Y ^{[1
]}

PELLON, P ^{[1
]}

LECORRE, M ^{[1
]}

机构：

[1] UNIV RENNES 1,CNRS,SYNTHESE ORGAN LAB,AVE GEN LECLERC,F-35042 RENNES,FRANCE

来源：

TETRAHEDRON LETTERS | 1993年 / 34卷 / 28期

关键词：

D O I：

10.1016/0040-4039(93)88075-T

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

An easy and soft method of decomplexation of phosphine-borane complexes, by DABCO, allows its use in situ in asymmetric catalytic hydrogenation of double bonds with metal phosphine complexes.

引用

页码：4523 / 4526

页数：4

共 12 条

[1] 1,4-BISMETHANESULFONATES OF STEREOISOMERIC BUTANETETRAOLS + RELATED COMPOUNDS [J].

FEIT, PW .

JOURNAL OF MEDICINAL CHEMISTRY, 1964, 7 (01) :14-+

[2] ACTIVATION OF PHOSPHINES WITH BORANE [J].

GOURDEL, Y ;

GHANIMI, A ;

PELLON, P ;

LECORRE, M .

TETRAHEDRON LETTERS, 1993, 34 (06) :1011-1012

[3] SYNTHESIS AND REACTIONS OF PHOSPHINE BORANES - SYNTHESIS OF NEW BIDENTATE LIGANDS WITH HOMOCHIRAL PHOSPHINE CENTERS VIA OPTICALLY PURE PHOSPHINE BORANES [J].

IMAMOTO, T ;

OSHIKI, T ;

ONOZAWA, T ;

KUSUMOTO, T ;

SATO, K .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1990, 112 (13) :5244-5252

[4] PHOSPHINE OXIDES AND LIAIH4-NABH4-CECL3 - SYNTHESIS AND REACTIONS OF PHOSPHINE-BORANES [J].

IMAMOTO, T ;

KUSUMOTO, T ;

SUZUKI, N ;

SATO, K .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1985, 107 (18) :5301-5303

[5] EFFICIENT ASYMMETRIC-SYNTHESIS OF OPTICALLY PURE TERTIARY MONO AND DIPHOSPHINE LIGANDS [J].

JUGE, S ;

STEPHAN, M ;

LAFFITTE, JA ;

GENET, JP .

TETRAHEDRON LETTERS, 1990, 31 (44) :6357-6360

[6] ASYMMETRIC CATALYTIC REDUCTION WITH TRANSITION-METAL COMPLEXES .1. CATALYTIC SYSTEM OF RHODIUM(I) WITH (-)-2,3-O-ISOPROPYLIDENE-2,3-DIHYDROXY-1,4-BIS(DIPHENYLPHOSPHINO)BUTANE - NEW CHIRAL DIPHOSPHINE [J].

KAGAN, HB ;

DANG, TP .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1972, 94 (18) :6429-&

[7]

MURRER BA, 1979, SYNTHESIS-STUTTGART, P350

[8] PHOSPHINE-BORANES IN SYNTHESIS - BORANE AS AN EFFICIENT PROTECTING GROUP IN THE PREPARATION OF FUNCTIONALIZED PHOSPHINES [J].

PELLON, P .

TETRAHEDRON LETTERS, 1992, 33 (31) :4451-4452

[9] NEW PHOSPHANEBORANE CHEMISTRY [J].

SCHMIDBAUR, H .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1980, 200 (01) :287-306

[10] PHOSPHANE-BORANE CHEMISTRY - OPEN-CHAIN AND CYCLIC PHOSPHANE-BORANES BASED ON TETRAMETHYLDIPHOSPHANE [J].

SCHMIDBAUR, H ;

WIMMER, T ;

GROHMANN, A ;

STEIGELMANN, O ;

MULLER, G .

CHEMISCHE BERICHTE, 1989, 122 (09) :1607-1612

← 1 2 →