MULTIPLE SPIN PROBE NMR-STUDIES OF IONIC STRUCTURE IN 1-METHYL-3-ETHYLIMIDAZOLIUM CHLORIDE ALCL3 MOLTEN-SALTS

被引：0

作者：

CARPER, WR ^{[1
]}

PFLUG, JL ^{[1
]}

WILKES, JS ^{[1
]}

机构：

[1] USAF ACAD,FRANK J SEILER RES LAB,COLORADO SPRINGS,CO 80840

来源：

INORGANICA CHIMICA ACTA | 1992年 / 193卷 / 02期

关键词：

D O I：

暂无

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The microdynamics of a room temperature molten salt system consisting of 1-methyl-3-ethylimidazolium chloride (MEICI), AlCl3 and NaCl is investigated by C-13, Na-23 and Al-27 NMR relaxation methods and viscosity measurements. This study supports the existence of a complex containing MEI+, AlCl4- and Na+. The dual spin probe (DSP) method is extended to Na-23, which has a liquid state quadrupole coupling constant of 1.0 MHz in this complex.

引用

页码：201 / 205

页数：5

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