ELIMINATION REARRANGEMENT IN BETA-FUNCTIONALIZED SILANES - THE DIRECTION OF THE REARRANGEMENT AND ITS SCOPE

被引：6
|
作者：
MENICHETTI, S
STIRLING, CJM
机构：
[1] UNIV SHEFFIELD,DEPT CHEM,SHEFFIELD S3 7HF,S YORKSHIRE,ENGLAND
[2] UNIV FLORENCE,DIPARTIMENTO CHIM ORGAN,I-50121 FLORENCE,ITALY
来源：
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2 | 1992年 / 05期
关键词：
D O I：
10.1039/p29920000741
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A new eliminative rearrangement of beta-silyl carbanions requires phenyl on carbon alpha- to silicon when the conjugate acid has a pK(a) (DMSO) in the range 12-30; rearrangement involves silicon and not phenyl migration.
引用
收藏
页码：741 / 742
页数：2
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