ELECTROORGANIC CHEMISTRY .134. FACILE ELECTROREDUCTION OF METHYL-ESTERS AND N,N-DIMETHYLAMIDES OF ALIPHATIC CARBOXYLIC-ACIDS TO PRIMARY ALCOHOLS

被引：43
|
作者：
SHONO, T
MASUDA, H
MURASE, H
SHIMOMURA, M
KASHIMURA, S
机构：
[1] Department of Synthetic Chemistry, Faculty of Engineering, Kyoto University, Kyoto 606-01, Yoshida, Sakyo
来源：
JOURNAL OF ORGANIC CHEMISTRY | 1992年 / 57卷 / 04期
关键词：
D O I：
10.1021/jo00030a003
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
In the presence of t-BuOH, methyl esters and N,N-dimethylamides of aliphatic carboxylic acids are electroreduced at a Mg cathode to the corresponding primary alcohols. In the presence of t-BuOD instead of t-BuOH, the electroreduction of the esters gives the corresponding 1,1-dideuterated alcohol. In all cases, the yields are excellent.
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页码：1061 / 1063
页数：3
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