ASYMMETRIC EPOXIDATION OF FLUORINATED ALLYLIC ALCOHOLS

被引：14

作者：

GOSMINI, C ^{[1
]}

DUBUFFET, T ^{[1
]}

SAUVETRE, R ^{[1
]}

NORMANT, JF ^{[1
]}

机构：

[1] UNIV PARIS 06,CHIM ORGANOELEMENTS LAB,TOUR 44-45,4 PL JUSSIEU,F-75252 PARIS 05,FRANCE

来源：

TETRAHEDRON-ASYMMETRY | 1991年 / 2卷 / 03期

关键词：

D O I：

10.1016/S0957-4166(00)82361-7

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The asymmetric epoxidation of an alpha, beta-difluoro primary allylic alcohol, and of two alpha-fluoro secondary allylic alcohols follows the pattern known with non fluorinated analogs. The fluoro epoxides thus formed can be transformed into chiral alpha-ketols and into an alpha-fluoroacid.

引用

页码：223 / 230

页数：8

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