PREPARATION OF PHOSPHONATED POLYPYRIDYL LIGANDS TO ANCHOR TRANSITION-METAL COMPLEXES ON OXIDE SURFACES - APPLICATION FOR THE CONVERSION OF LIGHT TO ELECTRICITY WITH NANOCRYSTALLINE TIO2 FILMS

被引:285
作者
PECHY, P [1 ]
ROTZINGER, FP [1 ]
NAZEERUDDIN, MK [1 ]
KOHLE, O [1 ]
ZAKEERUDDIN, SM [1 ]
HUMPHRYBAKER, R [1 ]
GRATZEL, M [1 ]
机构
[1] ECOLE POLYTECH FED LAUSANNE,INST CHIM PHYS,CH-1015 LAUSANNE,SWITZERLAND
关键词
D O I
10.1039/c39950000065
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
To anchor transition-metal compounds onto metal oxide surfaces 2,2':6',2''-terpyridine-4'-phosphonic acid (4'-PO3H2-terpy) is synthesized; strong surface adhesion as well as efficient charge-transfer sensitization of nanocrystalline TiO2 films has been observed with a ruthenium complex involving this ligand.
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页码:65 / 66
页数:2
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