A PRACTICAL CYCLOPROPANATION METHOD USING DIRECT GENERATION OF ORGANOZINC CARBENOIDS FROM CARBONYL-COMPOUNDS

被引：27

作者：

MOTHERWELL, WB

ROBERTS, LR

机构：

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1992年 / 21期

关键词：

D O I：

10.1039/c39920001582

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A variety of readily available aryl and alpha,beta-unsaturated carbonyl compounds, on treatment with zinc and 1,2-bis(chlorodimethylsilyl)ethane, afford organozinc carbenoids which may be trapped with alkenes to give cyclopropanes.

引用

页码：1582 / 1583

页数：2

共 11 条

[1] AN IMPROVED METHOD FOR THE GENERATION OF ORGANOZINC CARBENOIDS AND ITS APPLICATION IN DICARBONYL COUPLING REACTIONS
AFONSO, CAM
MOTHERWELL, WB
OSHEA, DM
ROBERTS, LR
[J]. TETRAHEDRON LETTERS, 1992, 33 (27) : 3899 - 3902
[2] OBSERVATIONS ON THE REDUCTIVE DEOXYGENATION OF ARYL AND ALPHA,BETA-UNSATURATED CARBONYL-COMPOUNDS WITH CHLOROTRIMETHYLSILANE AND ZINC
BANERJEE, AK
DECARRASCO, MCS
FRYDRYCHHOUGE, CSV
MOTHERWELL, WB
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1986, (24) : 1803 - 1805
[3] CYCLOPROPANES FROM REACTIONS OF TRANSITION-METAL CARBENE COMPLEXES WITH OLEFINS
BROOKHART, M
STUDABAKER, WB
[J]. CHEMICAL REVIEWS, 1987, 87 (02) : 411 - 432
[4] BURDEN J, 1986, J CHEM SOC CHEM COMM, P86
[5] DAVIES HML, 1991, COMPREHENSIVE ORGANI, V4, P1031
[6] ZINC REDUCTIONS IN PRESENCE OF ACIDS .2. CYCLOPROPANE FORMATION DURING REDUCTION OF AROMATIC-ALDEHYDES BY ZINC IN PRESENCE OF BORON-TRIFLUORIDE AND OLEFINS
ELPHIMOFFFELKIN, I
SARDA, P
[J]. TETRAHEDRON, 1975, 31 (22) : 2785 - 2789
[7] DIRECT DEOXYGENATION OF ALICYCLIC KETONES - NEW OLEFIN SYNTHESIS
MOTHERWELL, WB
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1973, (24) : 935 - 936
[8] Simmons H. E., 1973, ORG REACTIONS, V20, P1, DOI DOI 10.1002/0471264180.OR020.01
[9] TROST BM, 1991, COMPREHENSIVE ORGANI, V4, P951
[10] A NEW REACTION FOR THE SYNTHESIS OF CARBENE PRECURSORS FROM ALDEHYDES AND CP(CO)2FE(-)M(+) (M = NA, K)
VARGAS, RM
THEYS, RD
HOSSAIN, MM
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1992, 114 (02) : 777 - 778

← 1 2 →