SOLID-STATE MULTINUCLEAR NMR-STUDIES OF FERROELECTRIC, PIEZOELECTRIC, AND RELATED MATERIALS

被引：62
作者：
DEC, SF
DAVIS, MF
MACIEL, GE
BRONNIMANN, CE
FITZGERALD, JJ
HAN, SS
机构：
[1] COLORADO STATE UNIV,DEPT CHEM,FT COLLINS,CO 80523
[2] S DAKOTA STATE UNIV,DEPT CHEM,BROOKINGS,SD 57007
来源：
INORGANIC CHEMISTRY | 1993年 / 32卷 / 06期
关键词：
D O I：
10.1021/ic00058a034
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
High-field Ti-47 and Ti-49, Zn-67, Zr-92, and Ba-137 magic-angle-spinning NMR spectra are reported for the following ferroelectric, piezoelectric, and related materials: SrTiO3, BaTiO3, CaTiO3, TiO2, BaZrO3, SrZrO3, BaO, ZnO, and ZnS. The observed line shapes are rationalized in terms of the local symmetry of the various metal atom sites. An indication of the sensitivity of chemical shifts of the various metal cations to local chemical structure is given. in addition, H-1 CRAMPS NMR spectra of some zirconium and titanium salts that are used as precursors in the production of electrical materials are discussed.
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页码：955 / 959
页数：5
相关论文
共 40 条
[1]   REMEASUREMENT OF STRUCTURE OF HEXAGONAL ZNO [J].
ABRAHAMS, SC ;
BERNSTEIN, JL .
ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL CRYSTALLOGRAPHY AND CRYSTAL CHEMISTRY, 1969, B 25 :1233-+
[2]   REACTION OF ANATASE AND RUTILE WITH BARIUM CARBONATE [J].
AMIN, A ;
SPEARS, MA ;
KULWICKI, BM .
JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 1983, 66 (10) :733-738
[3]  
BLUMENTHAL WB, 1958, CHEM BEHAVIOR ZIRCON
[4]   COMBINED ROTATION AND MULTIPLE PULSE SPECTROSCOPY AS AN ANALYTICAL PROTON NUCLEAR MAGNETIC-RESONANCE TECHNIQUE FOR SOLIDS [J].
BRONNIMANN, CE ;
HAWKINS, BL ;
ZHANG, M ;
MACIEL, GE .
ANALYTICAL CHEMISTRY, 1988, 60 (17) :1743-1750
[5]   PROTON NMR-STUDY OF DEHYDRATION OF THE SILICA-GEL SURFACE [J].
BRONNIMANN, CE ;
ZEIGLER, RC ;
MACIEL, GE .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1988, 110 (07) :2023-2026
[6]  
Buchanan RC, 1986, CERAMIC MATERIALS EL
[7]   ANALYSIS OF MULTIPLE PULSE NMR IN SOLIDS .3. [J].
BURUM, DP ;
RHIM, WK .
JOURNAL OF CHEMICAL PHYSICS, 1979, 71 (02) :944-956
[8]   HIGH-TEMPERATURE PHASE TRANSITIONS IN SRZRO3 [J].
CARLSSON, L .
ACTA CRYSTALLOGRAPHICA, 1967, 23 :901-&
[9]   THE CRYSTAL STRUCTURE OF ZIRCONYL CHLORIDE OCTAHYDRATE AND ZIRCONYL BROMIDE OCTAHYDRATE [J].
CLEARFIELD, A ;
VAUGHAN, PA .
ACTA CRYSTALLOGRAPHICA, 1956, 9 (06) :555-558
[10]   NEUTRON-DIFFRACTION STUDY OF ZNS AND ZNTE [J].
COOPER, MJ ;
ROUSE, KD .
ACTA CRYSTALLOGRAPHICA SECTION A, 1973, 29 (JAN1) :49-56
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