STRIPPING VOLTAMMETRY OF METAL-COMPLEXES - INTERFERENCES FROM ADSORPTION ONTO CELL COMPONENTS

被引:44
作者
DIAZCRUZ, JM
ESTEBAN, M
VANDENHOOP, MAGT
VANLEEUWEN, HP
机构
[1] UNIV BARCELONA,DEPT ANALYT CHEM,AV DIAGONAL 647,E-08028 BARCELONA,SPAIN
[2] WAGENINGEN UNIV AGR,PHYS & COLLOID CHEM LAB,6703 HB WAGENINGEN,NETHERLANDS
关键词
D O I
10.1021/ac00041a007
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
The influence of the adsorption of metals by cell components on the voltammetric study of metal complexes was studied for the systems Zn/PMA and Cd/PMA (PMA, poly(methacrylic acid)) at different metal concentration levels. Glass, poly(fluoroethylene), Teflon, polymethacrylate, nylon, and polystyrene cells were tested in a wide range of pH values. The results of this work allowed the establishment of general guidelines and specific procedures to minimize the effect of adsorption in the study of such systems.
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页码:1769 / 1776
页数:8
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