SURFACE CATALYZED HYDROCHLORINATION OF 1,3-BUTADIENE

被引：4
|
作者：
MASCAVAGE, LM [1 ]
DALTON, DR [1 ]
机构：
[1] TEMPLE UNIV,DEPT CHEM,PHILADELPHIA,PA 19122
来源：
TETRAHEDRON LETTERS | 1991年 / 32卷 / 29期
关键词：
D O I：
10.1016/0040-4039(91)80806-H
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The rates of disappearance of gaseous hydrogen chloride (-d[HCl]/dt) and 1,3-butadiene and appearance of the gaseous products 3-chloro-1-butene and (E)- and (Z)-1-chloro-2-butene (+d[products]/dt) in Pyrex IR cells at 295 K and total initial pressures of about 450 torr are found to be proportional to the surface-to-volume ratio (S/V) of the reaction vessel.
引用
收藏
页码：3461 / 3464
页数：4
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