SYNTHESIS OF (S)-(+)-PARASORBIC ACID AND (S)-(+)-2-TRIDECANOL ACETATE - BAKERS-YEAST REDUCTIONS OF GAMMA-KETOSULFONES AND DELTA-KETOSULFONES

被引：47
作者：
GOPALAN, AS
JACOBS, HK
机构：
[1] Department of Chemistry, Plant Genetic Engineering Lab New Mexico State University Las Cruces
来源：
TETRAHEDRON LETTERS | 1990年 / 31卷 / 39期
关键词：
D O I：
10.1016/S0040-4039(00)97900-0
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The enantioselective reduction of 4-(p-toluenesulfonyl) butane-2-one and 5-(p-toluenesulfonyl) pentane-2-one with bakers' yeast gave the corresponding (S) alcohols in high optical purities and moderately good yields. The alcohol 2a was converted to (S)(+)parasorbic acid (4), while 2b was used for the preparation of (S)(+)-2-tridecanol acetate (7), using short synthetic sequences. © 1990.
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页码：5575 / 5578
页数：4
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