TRANSFER AND QUENCHING RATE CONSTANTS FOR XEF(III,1/2) AND XEF(II,3/2)

被引：47
作者：
BRASHEARS, HC
SETSER, DW
机构：
[1] Chemistry Department, Kansas State University, Manhattan
来源：
APPLIED PHYSICS LETTERS | 1978年 / 33卷 / 09期
关键词：
D O I：
10.1063/1.90541
中图分类号：
O59 [应用物理学];
学科分类号：
摘要：
Rate constants for transfer between XeF(III,1/2) and XeF(II,3/2) states and quenching of XeF(III,1/2) have been measured using a method which employs the steady-state photolysis of XeF2. For He, Ne, Ar, Kr, N2, CF4, and SF6 transfer dominates over quenching; for Xe, NF3, CF3Cl, and CF3H quenching and transfer are competitive. Only for F2 is quenching dominant. Based upon the relative emission intensities from XeF(III,1/2) and XeF(II,3/2) at high pressures of buffer gases, XeF(II,3/2) must be 0.08 eV lower in energy than XeF(III,1/2).
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页码：821 / 823
页数：3
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