REACTION OF 3,3-PENTAMETHYLENEDIAZIRIDINE WITH DIPHENYLCYCLOPROPENONE

被引：10

作者：

LOWN, JW

机构：

[1] Department of Chemistry, University of Alberta, Edmonton, Alta.

来源：

JOURNAL OF THE CHEMICAL SOCIETY C-ORGANIC | 1969年 / 10期

关键词：

D O I：

10.1039/j39690001338

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

3.3-Pentamethylenediaziridine reacts with diphenylcyclopropenone in methanol to give two isomeric 1 : 1 adducts. One of these is 1,2-dihydro-4,5-diphenylpyridazine-3-spirocyclohexan-6-one and to the second is tentatively ascribed the structure 2″,3″-diphenylcyclohexanespiro- 2′-oxadiazolidine-5′-spirocyclopropene on the basis of its conversion by a novel rearrangement back into an acylated diaziridine structure.

引用

页码：1338 / &