ROLE OF ACID AND BASE PROPERTIES OF V2O5-BASE METAL-OXIDE CATALYSTS FOR PARTIAL OXIDATION OF P-SUBSTITUTED TOLUENE

被引：0

作者：

UESHIMA, M ^{[1
]}

SAITO, N ^{[1
]}

SHIMIZU, N ^{[1
]}

机构：

[1] NIPPON SHOKUBAI CO LTD,CENT RES LAB,SUITA,OSAKA 564,JAPAN

来源：

ACID-BASE CATALYSIS II | 1994年 / 90卷

关键词：

D O I：

暂无

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The partial oxidation of p-methoxy toluene (PMT) to p-methoxy benzaldehyde (PMBA) in the vapor phase was effectively carried out over V2O5-base matal oxide (such as Tl2O or Cs2O),in which the catalytic activity and the selectivity are related to acid and base properties of the catalyst respectively. Furthermore, in selective oxidation reactions of various p-substituted toluene to corresponding benzaldehyde over V2O5-Tl2O, high selectivities were obtained. Reactivity of p-substituted toluene over this catalyst depended on the electron donating ability of the p-position substituted group. It was found that this catalyst was in molten state at reaction temperature.

引用

页码：59 / 66

页数：8

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