REDUCTION OF RUTHENIUM AND IRON MU-METHYLENE COMPLEXES WITH HYDROSILANES PRODUCING ALKANE - A MODEL SYSTEM FOR METHANATION VIA THE FISCHER-TROPSCH MECHANISM

被引：30

作者：

AKITA, M

OKU, T

HUA, R

MOROOKA, Y

机构：

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1993年 / 22期

关键词：

D O I：

10.1039/c39930001670

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Reduction of the Ru and Fe mu-methylene complexes [M2(C5H5)2(mu-CHR)(mu-CO)(CO)2] (2: M = Ru, R = H; 3: M = Fe, R = CH2Ph) with hydrosilanes produces alkane (RMe) by way of dinuclear hydrido-methylene and methyl intermediates as confirmed by the reaction of [Ru2(C5H5)2(mu-CHR)(mu-CO)(CO)(NCMe)] 9 with hydrosilanes; such a reaction sequence can be viewed as a model system for methanation via the Fischer-Tropsch mechanism.

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页码：1670 / 1672

页数：3

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