ELECTRON-AFFINITY OF CO(CO)(2)NO MEASURED BY NEGATIVE-ION PHOTOELECTRON-SPECTROSCOPY

被引：5

作者：

TURNER, NJ ^{[1
]}

MARTEL, AA ^{[1
]}

WALLER, IM ^{[1
]}

机构：

[1] UNIV BRITISH COLUMBIA,DEPT CHEM,VANCOUVER V6T 1Z1,BC,CANADA

来源：

JOURNAL OF PHYSICAL CHEMISTRY | 1994年 / 98卷 / 02期

关键词：

D O I：

10.1021/j100053a021

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

In this work, we present the fixed-frequency (at 355 nm) negative-ion photoelectron spectrum of Co(CO)(2)NO-. Analysis of the spectrum yields the electron affinity of Co(CO)(2)NO; EA[Co(CO)(2)NO] = 1.73 +/- 0.03 eV. The lack of extensive vibrational progressions in the spectrum is consistent with the neutral species and the negative-ion having similar equilibrium geometries.

引用

页码：474 / 477

页数：4

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