MOLECULAR-STRUCTURE OF THE CARBENOID YLIDIC COMPLEX, (C5H4ME)(CO)2MN[CHCH(PET3)]

被引：8
|
作者：
ROGERS, RD [1 ]
ALT, HG [1 ]
MAISEL, HE [1 ]
机构：
[1] UNIV BAYREUTH,ANORGAN CHEM LAB,W-8580 BAYREUTH,GERMANY
来源：
JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1990年 / 381卷 / 02期
基金：
美国国家科学基金会;
关键词：
D O I：
10.1016/0022-328X(90)80115-G
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The acetylene complex (C5H4Me)(CO)2Mn(C2H2 ) adds PEt3 to give the ylidic complex (C5H4Me)(CO)2Mn[CHCH(PEt3)] (1). An X-ray diffraction study of 1 reveals that the ylidic ligand is bonded to the metal in a carbenoid manner. © 1990.
引用
收藏
页码：233 / 238
页数：6
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