MOLECULAR-STRUCTURE OF THE CARBENOID YLIDIC COMPLEX, (C5H4ME)(CO)2MN[CHCH(PET3)]

被引:8
|
作者
ROGERS, RD [1 ]
ALT, HG [1 ]
MAISEL, HE [1 ]
机构
[1] UNIV BAYREUTH,ANORGAN CHEM LAB,W-8580 BAYREUTH,GERMANY
基金
美国国家科学基金会;
关键词
D O I
10.1016/0022-328X(90)80115-G
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The acetylene complex (C5H4Me)(CO)2Mn(C2H2 ) adds PEt3 to give the ylidic complex (C5H4Me)(CO)2Mn[CHCH(PEt3)] (1). An X-ray diffraction study of 1 reveals that the ylidic ligand is bonded to the metal in a carbenoid manner. © 1990.
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页码:233 / 238
页数:6
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