CRYSTAL AND MOLECULAR-STRUCTURE OF 4,N-DINITROBORNAN-2-IMINE (4,N-DINITROCAMPHORIMINE)

被引：11

作者：

CAMERON, TS ^{[1
]}

CORDES, RE ^{[1
]}

MORRIS, DG ^{[1
]}

MURRAY, AM ^{[1
]}

机构：

[1] UNIV GLASGOW,DEPT CHEM,GLASGOW G12 8QQ,SCOTLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2 | 1979年 / 03期

关键词：

D O I：

10.1039/p29790000300

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The title compound (1) is shown from a single-crystal X-ray diffraction study to exist in a configuration with the N(1)-N(2) and C(2)-C(3) bonds syn. Crystals are orthorhombic, space group P212121, with Z = 4 and a = 7.629(6), b = 7.729(5), c = 20.453(8); the structure was solved by direct methods and refined by full-matrix least squares to R 0.059 for 994 independent reflections. In the light of the configuration found for (1) we suggest that the previous mechanism for formation of nitro-imines be amended and propose a mechanism involving a radical pair intermediate.

引用

页码：300 / 303

页数：4

共 16 条

[1]

[Anonymous], 1974, INT TABLES XRAY CRYS, VIV, p[99, 149]

[2] SUBSTITUENT EFFECTS ON C-13 CHEMICAL-SHIFTS IN 1-SUBSTITUTED CAMPHENILONES AND SOME DERIVED N-NITRO-IMINES [J].