HYDROLYTIC BEHAVIOR OF GALLIUM(3) PERCHLORATE

被引：25

作者：

CRAIG, HR

TYREE, SY

机构：

[1] Department of Chemistry, College of William and Mary, Williamsburg, Virginia

来源：

INORGANIC CHEMISTRY | 1969年 / 8卷 / 03期

关键词：

D O I：

10.1021/ic50073a037

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Solutions of gallium(III) perchlorate at different base-to-gallium ratios and equilibrated at 50 and 75° have been studied. The data, along with characterization of the solid phase as GaOOH, indicate that equilibrium can be represented by the equation GaOOH(c) + 3Haq+ ⇄ Gaaq,3+ + 2H2O. The polymerization of the gallium solute species during the lengthy periods leading up to equilibrium is found to be a function of the ionic strength, the base ratio, and the initial polymerization number. Such variable behavior does not affect the nature of the ultimate equilibrium species. © 1969, American Chemical Society. All rights reserved.

引用

页码：591 / &

共 10 条

[1]

[Anonymous], 1967, POWDER DIFFRACTION F

[2] KINETICS OF CONDENSATION POLYMERIZATION [J].