REACTION OF O(1D2) WITH PROPYLENE

被引：17
作者：
KAJIMOTO, O
YAMASAKI, H
FUENO, T
机构：
[1] Department of Chemistry, Faculty of Engineering Science, Osaka University, Toyonaka, Osaka
来源：
CHEMICAL PHYSICS LETTERS | 1979年 / 68卷 / 01期
关键词：
D O I：
10.1016/0009-2614(79)80083-4
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The reaction of excited oxygen atom, O(1D2), with propylene has been studied under helium pressure up to 150 atm. The identified oxides and their limiting fractional yields are as follows: propylene oxide 0.22, propionaldehyde 0.22, acetone 0.11, allylalcohol 0.20, acrolein 0.02 and acetaldehyde 0.06. The mechanism of primary attack of O(1D2) on olefin is inferred on the basis of these figures. © 1979.
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页码：127 / 130
页数：4
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