共 21 条
[21]
SQUIRES RR, 1989, MOD INORG C, P43
CHEMISTRY OF COORDINATIVELY UNSATURATED AND ELECTRON DEFICIENT CARBONYL METALLATE IONS - GAS-PHASE REACTIONS OF [FE(CO)2]- WITH HYDROCARBONS
被引：9
作者：
GREGOR, IK
机构：
[1] School of Chemistry, The University of New South Wales, Kensington
关键词：
D O I：
10.1016/0022-328X(91)80123-2
中图分类号：
O61 [无机化学];
学科分类号：
070301 ;
081704 ;
摘要：
A study has been carried out of the gas phase reactions of the radical anion [Fe(CO)2]-. with twenty-one C2-C-8 hydrocarbons, including acyclic, cyclic and isomeric alkenes, dienes, alkynes, and aromatics. Dehydrogenation and decarbonylation processes have been identified in the principal reaction channels, which were dependent on the hydrocarbon structure, while sequential ligand substitutions were observed for the reaction of C2H2 with [Fe(CO)2]-. to give the terminal product ion [(C2H2)2.Fe]-.
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页码：257 / 263
页数：7
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