CHEMISTRY OF COORDINATIVELY UNSATURATED AND ELECTRON DEFICIENT CARBONYL METALLATE IONS - GAS-PHASE REACTIONS OF [FE(CO)2]- WITH HYDROCARBONS

被引：9

作者：

GREGOR, IK

机构：

[1] School of Chemistry, The University of New South Wales, Kensington

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1991年 / 415卷 / 02期

关键词：

D O I：

10.1016/0022-328X(91)80123-2

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A study has been carried out of the gas phase reactions of the radical anion [Fe(CO)2]-. with twenty-one C2-C-8 hydrocarbons, including acyclic, cyclic and isomeric alkenes, dienes, alkynes, and aromatics. Dehydrogenation and decarbonylation processes have been identified in the principal reaction channels, which were dependent on the hydrocarbon structure, while sequential ligand substitutions were observed for the reaction of C2H2 with [Fe(CO)2]-. to give the terminal product ion [(C2H2)2.Fe]-.

引用

收藏

页码：257 / 263

页数：7

相关论文

共 21 条

[1] THE GAS-PHASE CHEMISTRY OF TRANSITION-METAL IONS WITH ORGANIC-MOLECULES [J].

ALLISON, J .

PROGRESS IN INORGANIC CHEMISTRY, 1986, 34 :627-676

[2]

BUCHANAN MV, 1987, ACS S SERIES, V359

[3]

COLLMAN JP, 1987, PRINCIPLES APPLICATI

[4] FORMATION OF GAS-PHASE NEGATIVE-IONS IN FE(CO)5 AND NI(CO)4 [J].

COMPTON, RN ;

STOCKDALE, JAD .

INTERNATIONAL JOURNAL OF MASS SPECTROMETRY, 1976, 22 (1-2) :47-55

[5] HIGH FRONT-END AND BACK-END RESOLUTION MS MS IN FOURIER-TRANSFORM ION-CYCLOTRON RESONANCE MASS-SPECTROMETRY [J].

DEKONING, LJ ;

FOKKENS, RH ;

PINKSE, FA ;

NIBBERING, NMM .

INTERNATIONAL JOURNAL OF MASS SPECTROMETRY AND ION PROCESSES, 1987, 77 (01) :95-105

[6] LASER PHOTOELECTRON SPECTROMETRY OF THE NEGATIVE-IONS OF IRON AND IRON CARBONYLS - ELECTRON-AFFINITY DETERMINATION FOR THE SERIES FE(CO)N, N= 0, 1, 2, 3, 4 [J].

ENGELKING, PC ;

LINEBERGER, WC .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1979, 101 (19) :5569-5573

[7]

FREISER BS, 1988, TECHNIQUES STUDY ION, P61

[8] GAS-PHASE CHEMISTRY OF ELECTRON DEFICIENT ORGANOMETALLIC ANIONS - THE REACTIONS OF [CR(CO)3]-. AND [CR(CO)4]-. WITH ALDEHYDES, KETONES, ESTERS AND ETHERS [J].

GREGOR, IK .

ORGANIC MASS SPECTROMETRY, 1989, 24 (08) :529-534

[9] CHEMISTRY OF ELECTRON DEFICIENT ORGANOMETALLIC ANIONS - GAS-PHASE REACTIONS OF [CR(CO)3].- WITH AMINES [J].

GREGOR, IK .

INORGANICA CHIMICA ACTA, 1987, 132 (01) :3-5

[10] CHEMISTRY OF ELECTRON DEFICIENT CARBONYL METALLATE IONS - GAS-PHASE REACTIONS OF [METAL(CO)X]-, METAL=CR, MN - X=3, 4 AND [METAL(CO)Y]-, METAL=FE, NI - Y=2, 3 WITH CARBON-DISULFIDE [J].

GREGOR, IK .

INORGANICA CHIMICA ACTA, 1990, 176 (01) :19-22