STRUCTURE OF DI-2-PYRIDYL KETONE-HYDRATE PLATINUM(II) CHLORIDE TETRAHYDRATE

被引：20

作者：

SOMMERER, SO ^{[1
]}

ABBOUD, KA ^{[1
]}

机构：

[1] UNIV FLORIDA,DEPT CHEM,GAINESVILLE,FL 32611

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1993年 / 49卷

关键词：

D O I：

10.1107/S0108270192012496

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

An X-ray structural analysis of bis(di-2-pyridylmethanediol)platinum(II) dichloride tetrahydrate revealed a Pt(II) cation coordinated by four N-atom donors with two additional long-range O-atom interactions resulting in pseudo-octahedral geometry. The formation of a six-membered chelate in boat-like conformation together with the long-range off-axial interactions between Pt and O in the apical positions of the complex appear to contribute to the stability of the hydrated species.

引用

页码：1152 / 1154

页数：3

共 4 条

[1] NRCVAX - AN INTERACTIVE PROGRAM SYSTEM FOR STRUCTURE-ANALYSIS [J].