COMPARISON OF CALCIUM COMPLEXATION OF SOME CARBOXYLIC-ACIDS DERIVED FROM D-GLUCOSE AND D-FRUCTOSE

被引：26

作者：

BAZIN, H

BOUCHU, A

DESCOTES, G

PETITRAMEL, M

机构：

[1] UNIV LYON 1,LICAS,F-69622 VILLEURBANNE,FRANCE

[2] UNIV LYON 1,CHIM ORGAN LAB 2,CNRS,URA 463,F-69622 VILLEURBANNE,FRANCE

[3] CEI,F-69603 VILLEURBANNE,FRANCE

来源：

CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE | 1995年 / 73卷 / 08期

关键词：

CA(II) COMPLEXATION; CARBOXYLIC ACIDS; FRUCTOFURANOSIDES; FRUCTOPYRANOSIDES; GLUCOPYRANOSIDES;

D O I：

10.1139/v95-165

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The aim of this work was to compare calcium sequestering behaviour of 11 carboxylic acids derived from carbohydrates, and to study the influence of molecular structure on the calcium complexation. For this purpose, various carboxylic acids derived from methyl D-glucopyranoside, methyl D-fructopyranoside, and methyl D-fructofuranoside were synthesized and studied using an ion selective electrode to determine calcium complex formation constants. Complexation sites of carbohydrate skeletons were determined using C-13 NMR.

引用

页码：1338 / 1347

页数：10

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