MERCURIC ACETATE INDUCED FORMATION OF CYCLIC NITRONES FROM ALKENYL OXIMES

被引：38

作者：

GRIGG, R ^{[1
]}

HADJISOTERIOU, M ^{[1
]}

KENNEWELL, P ^{[1
]}

MARKANDU, J ^{[1
]}

THORNTONPETT, M ^{[1
]}

机构：

[1] ROUSSEL SCI INST, SWINDON SN3 5BZ, ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1992年 / 19期

关键词：

D O I：

10.1039/c39920001388

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Oximes possessing gamma- or delta-alkenyl substituents are cyclised by mercuric acetate to the corresponding cyclic nitrones; the mercurated nitrones undergo facially specific cycloaddition reactions with N-methylmaleimide to afford endo- and exo-cycloadducts, delta,delta'-bis(alkenyl) ketones undergo stereospecific cyclisation-intramolecular cycloaddition to furnish spirocyclic products.

引用

页码：1388 / 1389

页数：2

共 15 条

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