PYROLYSIS OF BENZENE NAPHTHALENE MIXTURES

被引：6

作者：

PEREZ, G ^{[1
]}

CRISTALLI, A ^{[1
]}

LILLA, E ^{[1
]}

机构：

[1] CNR,IST CHIM NUCL,AREA RIC,MONTEROTONDO,ITALY

来源：

CHEMOSPHERE | 1991年 / 22卷 / 3-4期

关键词：

D O I：

10.1016/0045-6535(91)90317-7

中图分类号：

X [环境科学、安全科学];

学科分类号：

08 ; 0830 ;

摘要：

Solutions of naphthalene in benzene were pyrolyzed under vacuum at 803 K. Biphenyls, isomeric terphenyls and phenylnaphthalenes, together with triphenylene and fluoranthene were found among the products. A kinetic treatment based upon the steady state approximations shows that the rate constants of similar processes do not differ very much each other. The presence of the two polycyclic aromatic hydrocarbons is ascribed to competitive reactions involving the radicalic intermediates.

引用

页码：279 / 284

页数：6

共 9 条

[1]

BADGER GM, 1965, PROGR PHYS ORG CHEM, V3, P1

[2] HIGH-PERFORMANCE LIQUID-CHROMATOGRAPHIC SEPARATION AND IDENTIFICATION OF PYROLYSIS PRODUCTS OF BENZENE [J].