PREPARATION AND X-RAY CRYSTAL-STRUCTURES OF VOLATILE COPPER(II) ALKOXIDES

被引：83

作者：

GOEL, SC ^{[1
]}

KRAMER, KS ^{[1
]}

CHIANG, MY ^{[1
]}

BUHRO, WE ^{[1
]}

机构：

[1] WASHINGTON UNIV,DEPT CHEM,ST LOUIS,MO 63130

来源：

POLYHEDRON | 1990年 / 9卷 / 04期

基金：

美国国家科学基金会;

关键词：

D O I：

10.1016/S0277-5387(00)86241-5

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Volatile amino-alkoxide complexes Cu[OCH2CH2NMe2]2 (1), Cu[OCHMeCH2 NMe2]2 (2) and Cu[OCH2CH2NMeCH2CH2NMe2]2 (3) have been prepared. X-ray crystal structures reveal a mononuclear, square-planar geometry for 2, and a mononuclear, distorted, square-pyramidal geometry for 3. Thermal decomposition (25-300°C) of 1 gives a mixture of copper, CuO and Cu2O whereas thermal decomposition of 2 gives copper. © 1990.

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页码：611 / 613

页数：3

相关论文

共 23 条

[1] Y1BA2CU3O7-DELTA FILM FORMATION BY AN OM-CVD METHOD [J].

ABE, H ;

TSURUOKA, T ;

NAKAMORI, T .

JAPANESE JOURNAL OF APPLIED PHYSICS PART 2-LETTERS & EXPRESS LETTERS, 1988, 27 (08) :L1473-L1475

[2] GROWTH OF SUPERCONDUCTING THIN-FILMS OF BISMUTH-STRONTIUM-CALCIUM-COPPER OXIDE BY ORGANOMETALLIC CHEMICAL VAPOR-DEPOSITION [J].

BERRY, AD ;

HOLM, RT ;

CUKAUSKAS, EJ ;

FATEMI, M ;

GASKILL, DK ;

KAPLAN, R ;

FOX, WB .

JOURNAL OF CRYSTAL GROWTH, 1988, 92 (1-2) :344-347

[3] FORMATION OF HIGH-TC SUPERCONDUCTING FILMS BY ORGANOMETALLIC CHEMICAL VAPOR-DEPOSITION [J].

BERRY, AD ;

GASKILL, DK ;

HOLM, RT ;

CUKAUSKAS, EJ ;

KAPLAN, R ;

HENRY, RL .

APPLIED PHYSICS LETTERS, 1988, 52 (20) :1743-1745

[4]

Bradley D. C., 1959, J APPL CHEM-USSR, V9, P435, DOI 10.1002/jctb.5010090810

[5] THE PYROLYSIS OF METAL ALKOXIDES .2. KINETIC STUDIES ON ZIRCONIUM TETRA-TERT-AMYLOXIDE [J].

BRADLEY, DC ;

FAKTOR, MM .

TRANSACTIONS OF THE FARADAY SOCIETY, 1959, 55 (12) :2117-2123

[6] MONOMERIC METAL-HYDROXIDES, ALKOXIDES, AND AMIDES OF THE LATE TRANSITION-METALS - SYNTHESIS, REACTIONS, AND THERMOCHEMISTRY [J].

BRYNDZA, HE ;

TAM, W .

CHEMICAL REVIEWS, 1988, 88 (07) :1163-1188

[7] CRYSTAL STRUCTURES OF HEXAAMMINECOPPER(2) HALIDES [J].

DISTLER, T ;

VAUGHAN, PA .

INORGANIC CHEMISTRY, 1967, 6 (01) :126-&

[8] A SOLUBLE COPPER(II) ALKOXIDE FOR SOLUTION-BASED SYNTHESES OF YBA2CU3O7-X [J].

GOEL, SC ;

KRAMER, KS ;

GIBBONS, PC ;

BUHRO, WE .

INORGANIC CHEMISTRY, 1989, 28 (19) :3619-3620

[9] CRYSTAL-STRUCTURE OF COPPER(I) TERT-BUTOXIDE [(CH3)3COCU]4 [J].

GREISER, T ;

WEISS, E .

CHEMISCHE BERICHTE-RECUEIL, 1976, 109 (09) :3142-3146

[10] SUBMICROMETER SUPERCONDUCTING YBA2CU3O6+X PARTICLES MADE BY A LOW-TEMPERATURE SYNTHETIC ROUTE [J].

HOROWITZ, HS ;

MCLAIN, SJ ;

SLEIGHT, AW ;

DRULINER, JD ;

GAI, PL ;

VANKAVELAAR, MJ ;

WAGNER, JL ;

BIGGS, BD ;

POON, SJ .

SCIENCE, 1989, 243 (4887) :66-69