A GENERAL PREPARATION OF HIGHLY FUNCTIONALIZED ZINC AND COPPER ORGANOMETALLICS AT THE ALPHA-POSITION TO AN OXYGEN

被引：43

作者：

CHOU, TS ^{[1
]}

KNOCHEL, P ^{[1
]}

机构：

[1] UNIV MICHIGAN,DEPT CHEM,WILLARD H DOW LABS,ANN ARBOR,MI 48109

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1990年 / 55卷 / 16期

关键词：

D O I：

10.1021/jo00303a007

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

α-Bromoalkyl acetates 2, which are readily prepared by the addition of acetyl bromide to aldehydes, insert zinc under mild conditions affording, after the addition of CuCN-2LiCl, polyfunctional a-acetoxy copper reagents of type 1. Their reactivity toward various organic electrophiles is described. © 1990, American Chemical Society. All rights reserved.

引用

页码：4791 / 4793

页数：3

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