N-MONOARYLDITHIOCARBAMATE COBALT(III) COMPLEXES

被引：8

作者：

KAUL, BB ^{[1
]}

PANDEYA, KB ^{[1
]}

机构：

[1] UNIV DELHI,DEPT CHEM,DELHI 110007,INDIA

来源：

TRANSITION METAL CHEMISTRY | 1979年 / 4卷 / 02期

关键词：

D O I：

10.1007/BF00618836

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Diamagnetic cobalt(III) complexes of the type (RHNCS2)3Co [R = Ph, XC6H4 (X=p-Me, p-OMe, p-Cl, p-Br and p-I) and 2,4-Me2C6H3] have been synthesised by reaction of the corresponding dithiocarbamate ammonium salts and hexaaquocobalt(II) chloride. Ligand field parameters calculated from visible spectral data indicate strong covalent character for the Co-S bond. The i.r. spectral data reveal that the CN bond in these dithiocarbamates has less double bond character compared to the corresponding dialkyldithiocarbamates. © 1979 Verlag Chemie, Gmbh.

引用

页码：112 / 114

页数：3

共 16 条

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