ASYMMETRIC EPOXIDATION AND KINETIC RESOLUTION OF ALLYLIC PHOSPHINE OXIDES

被引：20
|
作者：
CLAYDEN, J [1 ]
WARREN, S [1 ]
机构：
[1] UNIV CAMBRIDGE,CHEM LAB,CAMBRIDGE CB2 1EW,ENGLAND
来源：
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 1994年 / 19期
关键词：
D O I：
10.1039/p19940002811
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
a diphenylphosphinoyl group undergo asymmetric epoxidation with excellent enantioselectivity, and can undergo kinetic resolution with good diastereoselectivity, with the diphenylphosphinoyl group exerting an anti-directing effect on the epoxidation.
引用
收藏
页码：2811 / 2823
页数：13
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