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CRYSTAL AND MOLECULAR-STRUCTURE OF (TRI-TERT-BUTYL-ETA-5-CYCLOPENTADIENYL)(1,2,4-TRI-TERT-BUTYL-ETA-3-CYCLOPENTENYL)NICKEL
被引：12
|作者：
SCHNEIDER, JJ
KRUGER, C
机构：
[1] Max-Planck-Institut Für Kohlenforschung, Mulheim, W-4330
来源：
CHEMISCHE BERICHTE-RECUEIL
|
1992年
/
125卷
/
04期
关键词：
METAL VAPORIZATION;
ETA-5-ETA-3-SANDWICH COMPOUND;
SLIPPED SANDWICH STRUCTURE;
NICKEL SANDWICH COMPLEX;
D O I：
10.1002/cber.19921250415
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
(Tri-tert-butyl-eta(5)-cyclopentadienyl)(1,2,4-tri-tert-butyl-eta(3)-cyclopentenyl)nickel (1) is accessible by the metal vapor route. The molecule adopts a slipped sandwich structure in the solid state with the nickel atom eta(5)-eta(3)-coordinated to the five-membered rings. Its C-13-NMR data are reported together with data on (tert-butyl-eta(5)-cyclopentadienyl)(tert-butyl-eta(3)-cyclopentenyl)nickel 2 and (di-tert-butyl-eta(5)-cyclopentadienyl)(di-tert-butyl-eta(3)- cyclopentenyl)nickel 3.
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页码：843 / 845
页数：3
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