ANODIC-OXIDATION OF ISOPROPYL AND TERT-BUTYLBENZENES - SYNTHETIC ROUTES TO CERTAIN CYCLOHEXA-1,4-DIENES

被引：0
作者：
BARBA, I
TORNERO, M
机构：
来源：
TETRAHEDRON | 1992年 / 48卷 / 45期
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中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The anodic methoxylation of p-cymene and p-tert-butyltoluene afforded side-chain methoxylated products as well as nuclear-addition products. For nuclear-addition products both cis/trans isomers are possible and in both cases the cis isomer is in higher proportion than the trans one. The anodic methoxylation of 1,4-di-tert-butylbenzene af forded only nuclear-addition products and the anodic methoxylation of 1,4-di-isopropylbenzene afforded only side-chain products. A probable mechanism is provided.
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页码：9967 / 9976
页数：10
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