SUPPORTED AQUEOUS-PHASE, RHODIUM HYDROFORMYLATION CATALYSTS .1. NEW METHODS OF PREPARATION

被引：71

作者：

ARHANCET, JP

DAVIS, ME

HANSON, BE

机构：

[1] VIRGINIA POLYTECH INST & STATE UNIV,DEPT CHEM ENGN,BLACKSBURG,VA 24061

[2] VIRGINIA POLYTECH INST & STATE UNIV,DEPT CHEM,BLACKSBURG,VA 24061

来源：

JOURNAL OF CATALYSIS | 1991年 / 129卷 / 01期

基金：

美国国家科学基金会;

关键词：

D O I：

10.1016/0021-9517(91)90012-S

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Improved methods for the preparation of supported aqueous phase (SAP) catalysts are described. An in situ preparation of the supported rhodium complex and a more effective hydration procedure are presented. SAP catalysts are also prepared by a self-assembly experiment in which the separated components of a SAP catalyst spontaneously adopt a SAP configuration under reaction conditions. © 1991.

引用

页码：94 / 99

页数：6

共 4 条

[1] SUPPORTED AQUEOUS-PHASE CATALYSTS
ARHANCET, JP
DAVIS, ME
MEROLA, JS
HANSON, BE
[J]. JOURNAL OF CATALYSIS, 1990, 121 (02) : 327 - 339
[2] HYDROFORMYLATION BY SUPPORTED AQUEOUS-PHASE CATALYSIS - A NEW CLASS OF HETEROGENEOUS CATALYSTS
ARHANCET, JP
DAVIS, ME
MEROLA, JS
HANSON, BE
[J]. NATURE, 1989, 339 (6224) : 454 - 455
[3] HYDROFORMYLATION OF OLEFINS WITH THE WATER-SOLUBLE HRH(CO)[P(M-C6H4SO3NA)3]3 IN SUPPORTED AQUEOUS-PHASE - IS IT REALLY AQUEOUS
HORVATH, IT
[J]. CATALYSIS LETTERS, 1990, 6 (01) : 43 - 48
[4] HYDROFORMYLATION OF 1-HEPTENE BY A [RH(NBD)CL]2/PPH3 SYSTEM - A KINETIC APPROACH
ROYO, M
MELO, F
MANRIQUE, A
ORO, L
[J]. TRANSITION METAL CHEMISTRY, 1982, 7 (01) : 44 - 49

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