HALOGENATED PEROXYL RADICALS AS MULTIELECTRON OXIDANTS - PULSE-RADIOLYSIS STUDY ON THE REACTION OF TRICHLOROMETHYL PEROXYL RADICALS WITH IODIDE

被引：16

作者：

BONIFACIC, M ^{[1
]}

SCHONEICH, C ^{[1
]}

ASMUS, KD ^{[1
]}

机构：

[1] HAHN MEITNER INST BERLIN GMBH,BEREICH S,STRAHLENCHEM ABT,W-1000 BERLIN 39,GERMANY

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1991年 / 16期

关键词：

D O I：

10.1039/C39910001117

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

CCl3OO. radicals are shown to oxidize three equivalents of iodide ions to yield one l2 molecule (showing up as l3 - in aqueous solution) and one l. atom (showing up as l2.-) per peroxyl unit; the mechanism is considered to proceed via a protonated CCl3OO./l- adduct radical as the primary intermediate and subsequent nucleophilic (S(N)2) attack by a second iodide accompanied by electron localization in the hydroperoxide moiety leads to l2 and CCl3O. with the latter being responsible for the oxidation of the third iodide.

引用

页码：1117 / 1119

页数：3

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