ORGANOTIN(IV) POLYPYRAZOLYBORATES .8. HYDRIDOTRIS (4-CHLORO-3,5-DIMETHYL-1H-PYRAZOL-1-YL)BORATES - CHARACTERIZATION, MOSSBAUER STUDY AND X-RAY CRYSTAL-STRUCTURES OF [SNCL3(HB(4-CL-3,5-ME(2)PZ)(3)] AND [PHSNCL(2)(HB(4-CL-3,5-ME(2)PZ))(3)]

被引：20

作者：

LOBBIA, GG

CECCHI, P

CALOGERO, S

VALLE, G

CHIARINI, M

STIEVANO, L

机构：

[1] UNIV TUSCIA,DIPARTIMENTO AGROBIOL & AGROCHIM,I-01100 VITERBO,ITALY

[2] UNIV VENICE,DIPARTIMENTO CHIM FIS,I-30123 VENICE,ITALY

[3] CNR,CTR RIC BIOPOLIMERI,I-35100 PADUA,ITALY

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1995年 / 503卷 / 02期

关键词：

BORON; TIN; PYRAZOLYLBORATES; X-RAY STRUCTURE; MOSSBAUER; NMR SPECTROSCOPY;

D O I：

10.1016/0022-328X(95)05557-6

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Five tin(IV) and organotin(IV) hydridotris(4-chloro-3,5-dimethyl-1 H-pyrazol-1-yl)borates have been synthesized and characterized by H-1, C-13 and Sn-119 NMR and Sn-119m Mossbauer spectroscopy. The tin atom has a more or less distorted octahedral coordination both in the solid state and in solution. The X-ray crystal structures of trichlorotin(IV) and dichlorophenyltin(IV) hydridotris [4-chloro-3,5-dimethyl-1H- -pyrazol-1-yl)borates confirm these inferences.

引用

页码：297 / 305

页数：9

共 11 条

[1] A MOSSBAUER STUDY OF SOME IRON(II) AND IRON(III) POLY(PYRAZOLYL)-BORATES - THE X-RAY CRYSTAL-STRUCTURES OF IRON(II)BIS[HYDRIDOTRIS(3-METHYL-1H-PYRAZOL-1-YL)BORATE] AND IRON(III)BIS[HYDRIDOTRIS (1H-PYRAZOL-1-YL)BORATE] TETRAFLUOROBORATE [J].