PREPARATION AND PROPERTIES OF PALLADIUM(II) AND RHODIUM(I) COMPLEXES CONTAINING BIDENTATE PHOSPHINE SULFIDE AND SELENIDE LIGANDS

被引：12

作者：

CONTRERAS, R ^{[1
]}

VALDERRAMA, M ^{[1
]}

YANEZ, S ^{[1
]}

机构：

[1] CATHOLIC UNIV CHILE,FAC QUIM,DEPT NAT SCI,CASILLA 306,SANTIAGO,CHILE

来源：

TRANSITION METAL CHEMISTRY | 1993年 / 18卷 / 01期

关键词：

D O I：

10.1007/BF00136055

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The synthesis and properties of cationic complexes of general formula (ML2{CH2(Ph2PE)2)]BF4, where M = Pd(II) and Rh(II), L2 = eta3-MeC3H4, {P(O)(OR)2}2H (R = Me, Et), COD, (CO)2, (CO)PPh3 and E = S, Se are described. The methylene proton of the coordinated phosphine sulphide or selenide ligands react with strong bases as BuLi in n-hexane or NaH in THF, to give neutral complexes of the type [ML2{CH(Ph2PE)2)], where M = Pd(II), Rh(I); L2 = eta3-MeC3H4, COD and E = S, Se. The complexes have been characterized by elemental analyses, molar conductivities, i.r., H-1 n.m.r. and P-31{H-1} n.m.r. spectroscopy.

引用

页码：73 / 76

页数：4

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