ON THE SYNTHESIS OF ARYL CYCLOPROPANES FROM GAMMA-BENZENESULFONYLALKYL TIN DERIVATIVES AND NORMAL-BUTYLLITHIUM

被引：24
作者：
KRIEF, A
HOBE, M
机构：
[1] Department of Chemistry, Facultés Universitaires Notre-Dame de la Paix, B-5000 Namur
来源：
TETRAHEDRON LETTERS | 1992年 / 33卷 / 43期
关键词：
D O I：
10.1016/S0040-4039(00)79033-2
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Gamma-Benzenesulfonyloxyalkyl tin derivatives readily available from gamma-hydroxyalkyl selenides, n-butyllithium and trialkyl tin chlorides react with n-butyllithium and stereospecifically lead to aryl cyclopropanes. The transformation is quite general and allows the synthesis of alpha,beta-di- and trisubstituted ones.
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页码：6527 / 6528
页数：2
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