CHAIN TRANSFER-REACTION BY TRIMETHYLVINYLSILANE IN THE POLYMERIZATION OF SUBSTITUTED ACETYLENES

被引：6

作者：

MASUDA, T

KOUZAI, H

HIGASHIMURA, T

机构：

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1991年 / 04期

关键词：

D O I：

10.1039/c39910000252

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Trimethylvinylsilane works as an effective chain transfer agent in the polymerisation of various substituted acetylenes by Mo and W catalysts, which enables the control of polymer molecular weight and verifies the metal-carbene mediated polymerisation mechanism.

引用

页码：252 / 253

页数：2

共 7 条

[1]

COSTA G, 1989, COMPREHENSIVE POLYM, V4, pCH1

[2]

Ivin K J., 1983, OLEFIN METATHESIS

[3] MECHANISMS OF PHENYLACETYLENE POLYMERIZATION BY MOLYBDENUM AND TITANIUM INITIATORS [J].