EVALUATION OF MICROWAVE DIGESTION FOR CHEMICAL OXYGEN-DEMAND DETERMINATION

被引:16
作者
DELVALLE, M
POCH, M
ALONSO, J
BARTROLI, J
机构
[1] Química Analítica, Facultat de Ciències, Universitat Autònoma de Barcelona, Bellaterra
[2] Enginyería Química, Facultat de Ciències, Universitat Autònoma de Barcelona, Bellaterra
关键词
D O I
10.1080/09593339009384963
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
A microwave digestion procedure has been evaluated for use in the determination of chemical oxygen demand (COD) by the dichromate method, using small volumes of sample and reagents. Different organic substances with COD values between 50 and 500 mg O2.1(-1) were analyzed by both the proposed procedure and the standard method, obtaining satisfactory results (mean recoveries 91-102%) with digestion times lower than 5 min. Samples of river water and wastewater were also analyzed, obtaining results showing good agreement with the standard method.
引用
收藏
页码:1087 / 1092
页数:6
相关论文
共 22 条
[1]   WET ASHING OF SOME BIOLOGICAL SAMPLES IN A MICROWAVE OVEN [J].
ABUSAMRA, A ;
MORRIS, JS ;
KOIRTYOHANN, SR .
ANALYTICAL CHEMISTRY, 1975, 47 (08) :1475-1477
[2]  
ALVARADO J, 1988, ANAL LETT, V21, P357
[3]  
[Anonymous], 1985, STANDARD METHODS EXA
[4]  
APPLETON JMH, 1986, ANAL CHIM ACTA, V179, P269, DOI 10.1016/S0003-2670(00)84471-2
[5]   MICROWAVE OVEN-BASED WET DIGESTION TECHNIQUE [J].
BARRETT, P ;
DAVIDOWSKI, LJ ;
PENARO, KW ;
COPELAND, TR .
ANALYTICAL CHEMISTRY, 1978, 50 (07) :1021-1023
[6]   FLOW-INJECTION AND MICROWAVE-OVEN SAMPLE DECOMPOSITION FOR DETERMINATION OF COPPER, ZINC AND IRON IN WHOLE-BLOOD BY ATOMIC-ABSORPTION SPECTROMETRY [J].
BURGUERA, M ;
BURGUERA, JL ;
ALARCON, OM .
ANALYTICA CHIMICA ACTA, 1986, 179 :351-357
[7]  
Devaraj M., 1988, P159
[8]   RAPID AND PRECISE METHOD FOR THE DETERMINATION OF THE CHEMICAL OXYGEN-DEMAND OF FACTORY EFFLUENT SAMPLES [J].
EDWARDS, SJ ;
ALLEN, M .
ANALYST, 1984, 109 (05) :671-672
[9]   CLOSED-VESSEL MICROWAVE DISSOLUTION AND COMPREHENSIVE ANALYSIS OF STEEL BY DIRECT-CURRENT PLASMA ATOMIC EMISSION-SPECTROMETRY [J].
FERNANDO, LA ;
HEAVNER, WD ;
GABRIELLI, CC .
ANALYTICAL CHEMISTRY, 1986, 58 (02) :511-512
[10]  
HASEK JA, 1974, ANAL CHEM, V46, P1160