TRANSANNULARLY BRIDGED DI-MU-2-THIOTETRABORANE(10) - DYNAMICS, CIS TRANS-ISOMERISM, REVERSIBLE REARRANGEMENT - BIS(DIBORANYL) BUTTERFLY STRUCTURE

被引：2

作者：

BINDER, H

MELIDIS, P

SOYLEMEZ, S

HECKMANN, G

机构：

[1] Institute of Inorganic Chemistry, University of Stuttgart, D-7000 Stuttgart 80

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1991年 / 16期

关键词：

D O I：

10.1039/C39910001091

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

B4H10 reacts with bifunctional thiols to give transannularly bridged H-2(mu-2)2S2RBH(B2H5) which exists as cis-trans isomers; on cooling these compounds rearrange to cis-trans H2B(mu-2)2S2RB3H6.

引用

页码：1091 / 1093

页数：3

共 2 条

[1] X-RAY MOLECULAR-STRUCTURE OF ASYMMETRICALLY BRIDGED ESTER COMPLEX DI-MU-OXO-BIS[(CYCLOHEXANE-1,2-DIOLATO)OXO(QUINUCLIDINE)OSMIUM(VI)], [OSO2(O2C6H10)(C7H13N)]2
CARTWRIGHT, BA
GRIFFITH, WP
SCHRODER, M
SKAPSKI, AC
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1978, (19) : 853 - 854
[2] SYNTHESIS AND CHARACTERIZATION OF CYCLOMETALATED PALLADIUM(II) COMPLEXES WITH PH2PCH2PPH2 (DPPM), TRANS-PH2PCH=CHPPH2 (TRANS-DPPE), CIS-PH2PCH=CHPPH2 (CIS-DPPE) AND PH2P(CH2)4PPH2 (DPPB) - THE X-RAY CRYSTAL-STRUCTURE OF DI-MU-BROMO-BIS[N-(4-METHYLBENZYLIDENE)CYCLOHEXYLAMINATO-C6,N]DIPALLADIUM(II)
VILA, JM
GAYOSO, M
PEREIRA, MT
ORTIGUEIRA, JM
FERNANDEZ, A
BAILEY, NA
ADAMS, H
POLYHEDRON, 1993, 12 (02) : 171 - 180

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