Ammonothermal Synthesis and Crystal Structures of Diamminetriamidodizinc Chloride [Zn-2(NH3)(2)(NH2)(3)]Cl and Diamminemonoamidozinc Bromide [Zn(NH3)(2)(NH2)]Br

被引：3
|
作者：
Richter, Theresia M. M. [1 ]
Strobel, Sabine [1 ]
Alt, Nicolas S. A. [2 ]
Schluecker, Eberhard [2 ]
Niewa, Rainer [1 ]
机构：
[1] Univ Stuttgart, Inst Inorgan Chem, Pfaffenwaldring 55, D-70569 Stuttgart, Germany
[2] Univ Erlangen Nurnberg, Inst Proc Machinery & Syst Engn, Cauerstr 4, D-91058 Erlangen, Germany
来源：
INORGANICS | 2016年 / 4卷 / 04期
关键词：
ammonothermal synthesis; amides; ammoniates; zinc;
D O I：
10.3390/inorganics4040041
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The treatment of excess zinc in the presence of ammonium chloride under ammonothermal conditions of 873 K and 97 MPa leads to diamminetriamidodizinc chloride [Zn-2(NH3)(2)(NH2)(3)]Cl with a two-dimensionally mu-amido-interconnected substructure. Similar reaction conditions using ammonium bromide instead of the chloride (773 K, 230 MPa) result in diamminemonoamidozinc bromide [Zn(NH3)(2)(NH2)]Br with one-dimensional infinite mu-amido-bridged chains. Both compounds were obtained as colorless, very moisture sensitive crystals. Crystal structures and hydrogen bond schemes are analyzed. Raman spectroscopic data of the chloride are reported.
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页数：10
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