CRYSTAL-STRUCTURE OF BIS(1-THIA-4,7-DIAZACYCLONONANE)COPPER(II) PERCHLORATE

被引：10

作者：

GAHAN, LR

KENNARD, CHL

SMITH, G

MAK, TCW

机构：

[1] QUEENSLAND INST TECHNOL,DEPT CHEM,BRISBANE,QLD 4000,AUSTRALIA

[2] CHINESE UNIV HONG KONG,DEPT CHEM,SHATIN,HONG KONG

来源：

TRANSITION METAL CHEMISTRY | 1986年 / 11卷 / 12期

关键词：

CRYSTALS; -; Structure; SALTS;

D O I：

10.1007/BF01386877

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The cation, bis(1-thia-4,7-diazacyclononane)copper(II), in the perchlorate salt, has the metal on a crystallographic twofold axis, and is dissimilar to the nitrate, where the metal is a center of symmetry. The nitrate anion is directly involved in a hydrogen bond with one N-H of each ligand while the packing of left bracket Cu(tasn)//2 right bracket (ClO//4)//2 in the unit cell involves no significant inter-ion interactions between complex cations and the perchlorate anions. The same labeling has been used as for the nitrate.

引用

页码：465 / 466

页数：2