AN UNUSUAL SUPPRESSION OF TRIMETHYLAMINE FORMATION IN THE HIGH-TEMPERATURE ALKYLATION OF AMMONIA WITH METHANOL OVER (NH4)3PW12O40

被引：6

作者：

NASIKIN, M

NAKAMURA, R

NIIYAMA, H

机构：

[1] TOKYO INST TECHNOL, INT COOPERAT CTR SCI & TECHNOL, OOKAYAMA, MEGURO KU, TOKYO 152, JAPAN

[2] TOKYO INST TECHNOL, FAC ENGN, DEPT CHEM ENGN, MEGURO KU, TOKYO 152, JAPAN

来源：

CHEMISTRY LETTERS | 1993年 / 02期

关键词：

D O I：

10.1246/cl.1993.209

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A synthesis of methylamines from ammonia and methanol was studied by using mainly the title heteropoly catalyst. Although at low temperatures below ca. 750 K the three methylamines (MMA, DMA, and TMA) were formed as usual, at higher temperatures the formation of TMA was completely suppressed. This unusual product selectivity was explained by the strong adsoption of TMA to the catalyst.

引用

页码：209 / 212

页数：4

共 30 条

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Satam, Jitendra R.
Jayaram, Radha V.
SYNTHETIC COMMUNICATIONS, 2008, 38 (04) : 595 - 602
[2] Preparation of BiOCl-(NH4)3PW12O40 Photocatalyst and a Mechanism for Photocatalytic Degradation of Organic Pollutants
Zhang W.-H.
Ji Q.-H.
Lan H.-C.
Li J.
Huanjing Kexue/Environmental Science, 2019, 40 (03): : 1295 - 1301
[3] Porous Aggregates of Unidirectionally Oriented (NH4)3PW12O40 Microcrystallites: Epitaxial Self-Assembly
Inumaru, K.
Nakajima, H.
Ito, T.
Misono, M.
Chemistry Letters, (07):
[4] ZrO2-（NH4）3PW12O40光催化降解罗丹明B
冯少凡
李征
李芳
郝泽坤
胡乐
李静
化工环保, 2022, 42 (02) : 225 - 230
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Sahiro, Koichi
Ide, Yusuke
Sano, Tsuneji
Sadakane, Masahiro
MATERIALS RESEARCH BULLETIN, 2013, 48 (10) : 4157 - 4162
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Ito, T
Inumaru, K
Misono, M
CHEMISTRY OF MATERIALS, 2001, 13 (03) : 824 - 831
[7] Novel microstructures of self-assembled microcrystallites of (NH4)(3)PW12O40 and Cs3PW12O40
Ito, T
Song, IK
Inumaru, K
Misono, M
CHEMISTRY LETTERS, 1997, (08) : 727 - 728
[8] Sponge Crystal:: a novel class of microporous single crystals formed by self-assembly of polyoxometalate (NH4)3PW12O40 nanocrystallites
Inumaru, Kei
CATALYSIS SURVEYS FROM ASIA, 2006, 10 (3-4) : 151 - 160
[9] “Sponge Crystal”: a novel class of microporous single crystals formed by self-assembly of polyoxometalate (NH4)3PW12O40 nanocrystallites
Kei Inumaru
Catalysis Surveys from Asia, 2006, 10 : 151 - 160
[10] SINGULAR BEHAVIOR OF H3PW12O40 AT HIGH-TEMPERATURE - EVIDENCE FOR THE FORMATION OF AN ANHYDRIDE PHASE
OULMEKKI, A
OLIVIER, D
HERVE, G
LEFEBVRE, F
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