AN INTRAMOLECULAR HYDROSILATION APPROACH TO HEXAHYDROOXONINS RELATED TO OBTUSENYNE - EFFECT OF CATALYST AND CONDITIONS ON STEREOSELECTIVITY

被引：28

作者：

CURTIS, NR ^{[1
]}

HOLMES, AB ^{[1
]}

机构：

[1] UNIV CAMBRIDGE,CHEM LAB,LENSFIELD RD,CAMBRIDGE CB2 1EW,ENGLAND

来源：

TETRAHEDRON LETTERS | 1992年 / 33卷 / 05期

关键词：

MEDIUM RING; INTRAMOLECULAR HYDROSILATION; ALPHA-HYDROXY ENOL ETHER; HEXAHYDROOXONIN; STEREOSELECTIVITY;

D O I：

10.1016/S0040-4039(00)92340-2

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The intramolecular hydrosilation of the alpha-dialkysilyloxy enol ethers 3 and 5 followed by oxidative work-up resulted in the diastereoselective synthesis of either the hexahydrooxonin diol 7 or 8 according to the catalyst and conditions employed.

引用

页码：675 / 678

页数：4

共 3 条

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