ELECTRONIC-PROPERTIES OF SUPPORTED PD AGGREGATES IN RELATION WITH THEIR REACTIVITY FOR 1,3-BUTADIENE HYDROGENATION

被引:91
|
作者
BERTOLINI, JC
DELICHERE, P
KHANRA, BC
MASSARDIER, J
NOUPA, C
TARDY, B
机构
[1] Institut de Recherches sur la Catalyse, C.N.R.S., Villeurbanne Cedex, 69626
关键词
aggregates 1,3 butadiene; binding energy; FWHM; hydrogenation reaction; supported Pd; TOF; XPS;
D O I
10.1007/BF00774723
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The electronic and catalytic properties of supported Pd particles have been studied by measurements of XPS core level shifts and activity for 1,3-butadiene hydrogenation reaction respectively. For samples prepared by atom beam deposition on carbonaceous supports the TOF at steady state decreases rapidly with decreasing particle size in the range of particle diameter 2.8 nm-1.2 nm. For these small particles, the Pd 3d core level shows an upwards shift and a larger half width compared to the values for massive Pd samples. For the Pd/SiO2 particles of similar size, both the 3d core level energy and the TOF are comparable to these of the massive Pd systems. © 1990 J.C. Baltzer A.G. Scientific Publishing Company.
引用
收藏
页码:215 / 223
页数:9
相关论文
共 50 条
  • [31] HYDROGENATION OF 1-BUTENE AND 1,3-BUTADIENE MIXTURES OVER PD/ZNO CATALYSTS
    SARKANY, A
    ZSOLDOS, Z
    FURLONG, B
    HIGHTOWER, JW
    GUCZI, L
    JOURNAL OF CATALYSIS, 1993, 141 (02) : 566 - 582
  • [32] THE HYDROGENATION OF 1,3-BUTADIENE OVER A PALLADIUM MEMBRANE
    NAGAMOTO, H
    INOUE, H
    BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1986, 59 (12) : 3935 - 3939
  • [33] VARIETIES OF MGO CATALYSTS FOR 1,3-BUTADIENE HYDROGENATION
    MIYAHARA, K
    MURATA, Y
    TOYOSHIMA, I
    TANAKA, Y
    YOKOYAMA, T
    JOURNAL OF CATALYSIS, 1981, 68 (01) : 186 - 189
  • [34] Novel AuPd nanostructures for hydrogenation of 1,3-butadiene
    Chen, Huimei
    Huang, Jiale
    Huang, Dengpo
    Sun, Daohua
    Shao, Minhua
    Li, Qingbiao
    JOURNAL OF MATERIALS CHEMISTRY A, 2015, 3 (09) : 4846 - 4854
  • [36] GENOTOXIC PROPERTIES OF 1,3-BUTADIENE
    DEMEESTER, C
    MUTATION RESEARCH, 1988, 195 (03): : 273 - 281
  • [37] The reactivity of 1,3-butadiene with butadiene-derived popcorn polymer
    Levin, ME
    Hill, AD
    Zimmerman, LW
    Paxson, TE
    JOURNAL OF HAZARDOUS MATERIALS, 2004, 115 (1-3) : 71 - 90
  • [38] Pd deposited on Cu(110): a highly performant catalyst for the 1,3-butadiene hydrogenation reaction
    Constant, L
    Ruiz, P
    Abel, M
    Robach, Y
    Porte, L
    Bertolini, JC
    TOPICS IN CATALYSIS, 2001, 14 (1-4) : 125 - 129
  • [39] Pd deposited on Cu(110): A highly performant catalyst for the 1,3-butadiene hydrogenation reaction
    Constant L.
    Ruiz P.
    Abel M.
    Robach P.
    Porte L.
    Bertolini J.C.
    Topics in Catalysis, 2000, 14 (1-4) : 125 - 129
  • [40] Effect of hydrocarbonaceous deposits on competitive hydrogenation of 1,3-butadiene and propene over Pd catalyst
    Sarkany, A
    JOURNAL OF CATALYSIS, 1998, 180 (02) : 149 - 152