CALCIUM NICKEL ORTHOPHOSPHATE - CRYSTAL-STRUCTURE OF CA8.5NI9.5(PO4)(12)

被引：5
|
作者：
ELBALI, B
BOUKHARI, A
HOLT, EM
ARIDE, J
机构：
[1] OKLAHOMA STATE UNIV,DEPT CHEM,STILLWATER,OK 74078
[2] UNIV MOHAMMED 5,FAC SCI,DEPT CHIM,CHIM SOLIDE APPL LAB,RABAT,MOROCCO
[3] ENS TAKADDOUM,PHYSICOCHIM MAT LAB,RABAT,MOROCCO
来源：
ZEITSCHRIFT FUR KRISTALLOGRAPHIE | 1995年 / 210卷 / 11期
关键词：
ORTHOPHOSPHATES; CRYSTAL STRUCTURE;
D O I：
10.1524/zkri.1995.210.11.838
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
A calcium nickel orthophosphate complex has been isolated and shown to display a solid state structure similar to that of alpha-Ca-3(PO4)(3) with columns of cations surrounded by (PO4)-nickel-(PO4)-vacancy columns in hexagonal array. Calcium and nickel atoms are distributed within the cation columns. Ca8.5Ni9.5(PO4)(12) (space group C2/c, a = 22.819(5) Angstrom, b = 9.944(2) Angstrom, c = 16.982(3) Angstrom, beta = 99.97(3)degrees, D-calc = 3.67 g cm(-3), Z = 4, R = 5.59% for 3216 obs. refls.) shows cation columns to contain 29.2% nickel and 70.8% calcium atoms.
引用
收藏
页码：838 / 842
页数：5
相关论文
共 50 条
  • [1] Crystal structure of calcium cobalt orthophosphate, CaCo[Ca0.1Co0.9](PO4)2
    Fukuda, Koichiro
    Hasegawa, Hajime
    Iwata, Tomoyuki
    Hashimoto, Shinobu
    POWDER DIFFRACTION, 2006, 21 (03) : 220 - 224
  • [2] Synthesis and crystal structure of Ca9Cu1.5(PO4)7 and reinvestigation of Ca9.5Cu(PO4)7
    Belik, AA
    Yanov, OV
    Lazoryak, BI
    MATERIALS RESEARCH BULLETIN, 2001, 36 (10) : 1863 - 1871
  • [3] Synthesis and crystal structure of calcium dizinc iron(III) tris(orthophosphate), CaZn2Fe(PO4)(3)
    Khmiyas, Jamal
    Assani, Abderrazzak
    Saadi, Mohamed
    El Ammari, Lahcen
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2016, 72 : 1260 - +
  • [4] Crystal structure of silver strontium copper orthophosphate, AgSr4Cu4.5(PO4)6
    Khmiyas, Jamal
    Benhsina, Elhassan
    Ouaatta, Said
    Assani, Abderrazzak
    Saadi, Mohamed
    El Ammari, Lahcen
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2020, 76 : 186 - +
  • [5] THE CRYSTAL-STRUCTURE OF MONOCLINIC AG5CU3(PO4)2((PO4)H(PO4)) AND ITS RELATIONSHIP TO THE TRICLINIC SODIUM ANALOG
    EFFENBERGER, H
    PERTLIK, F
    ZEITSCHRIFT FUR KRISTALLOGRAPHIE, 1991, 194 (3-4): : 207 - 219
  • [6] Synthesis and crystal structure of calcium copper phosphate, s-Ca19Cu2(PO4)(14)
    Khan, N
    Morozov, VA
    Khasanov, SS
    Lazoryak, BI
    MATERIALS RESEARCH BULLETIN, 1997, 32 (09) : 1211 - 1220
  • [7] Crystal structure of lead dinickel iron tris(orthophosphate): PbNi2Fe(PO4)3
    Ouaatta, S.
    Benhsina, E.
    Khmiyas, J.
    Assani, A.
    Saadi, M.
    El Ammari, L.
    ACTA CRYSTALLOGRAPHICA A-FOUNDATION AND ADVANCES, 2021, 77 : C1027 - C1027
  • [8] Crystal structure of barium dinickel(II) iron(III) tris[orthophosphate(V)], BaNi2Fe(PO4)3
    Ouaatta, Said
    Bouraima, Adam
    Benhsina, Elhassan
    Khmiyas, Jamal
    Assani, Abderrazzak
    Saadi, Mohamed
    El Ammari, Lahcen
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2023, 79 : 95 - +
  • [9] Synthesis and crystal structure of complex [Ni(en)3]4[HVIV12VV6O42(PO4)]
    Zheng, ST
    Zeng, QX
    Lin, ZE
    Yang, GY
    CHINESE JOURNAL OF INORGANIC CHEMISTRY, 2002, 18 (12) : 1233 - 1236
  • [10] Crystal structure of strontium dicobalt iron(III) tris(orthophosphate): SrCo2Fe(PO4)(3)
    Bouraima, Adam
    Makani, Thomas
    Assani, Abderrazzak
    Saadi, Mohamed
    El Ammari, Lahcen
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2016, 72 : 1143 - +
12345