DILITHIUM ACEPENTALENEDIIDE - AN UNUSUAL DIMER OF CONTACT ION TRIPLETS WITH BOWL-SHAPED DIANIONS

被引：32
作者：
HAAG, R
FLEISCHER, R
STALKE, D
DEMEIJERE, A
机构：
[1] UNIV GOTTINGEN,INST ANORGAN CHEM,D-37077 GOTTINGEN,GERMANY
[2] UNIV GOTTINGEN,INST ORGAN CHEM,D-37077 GOTTINGEN,GERMANY
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1995年 / 34卷 / 13-14期
关键词：
ACEPENTALENES; FULLERENES; PENTALENES; STRUCTURE ELUCIDATION;
D O I：
10.1002/anie.199514921
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Pure 4,7‐bis(trimethylstannyl)dihydroacepentalene 1 can be transformed cleanly into dilithium acepentalenediide 2 by treatment with methyllithium. In the crystal 2 adopts an interesting dimeric structure in which the convex sides of the two bowl‐shaped dianionic fragments face each other. (Figure Presented.) Copyright © 1995 by VCH Verlagsgesellschaft mbH, Germany
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页码：1492 / 1495
页数：4
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