Crystal structure of 1,2-bis[(1H-imidazol-2-yl)methylidene] hydrazine and its one-dimensional hydrogen-bonding network

被引:0
|
作者
Lee, Chia-Hwa [1 ]
Lee, Gene-Hsiang [2 ]
机构
[1] Natl Taiwan Univ, Dept Chem, Taipei 10764, Taiwan
[2] Natl Taiwan Univ, Instrumentat Ctr, Taipei 10764, Taiwan
关键词
crystal structure; imidazole derivative; hydrogen bonding; supramolecular architecture;
D O I
10.1107/S2056989016004497
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
In the title compound, C8H8N6, two imidazolyl groups are separated by a zigzag -CH=N-N=CH-linkage. An inversion center is located at the mid-point of the N-N single bond and the complete molecule is generated by symmetry. In the crystal, each molecule forms four N-H center dot center dot center dot N hydrogen bonds with two neighbouring molecules to constitute a one-dimensional ladder-like structure propagating along the a-axis direction.
引用
收藏
页码:556 / +
页数:6
相关论文
共 50 条
  • [1] The hydrogen-bonding network in (E)-1,2-bis(1-ethylbenzimidazol-2-yl)ethene dihydrate
    Stibrany, RT
    Potenza, JA
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2006, 62 : O828 - O830
  • [2] 1,2-Bis[(1,3-benzodioxol-5-yl)methylidene]hydrazine
    Jasinski, Jerry P.
    Golen, James A.
    Praveen, A. S.
    Narayana, B.
    Yathirajan, H. S.
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2012, 68 : O7 - +
  • [3] Synthesis and Crystal Structure of a One-Dimensional Chain Cadmium Coordination Polymer Bridged Through 1,2-bis(imidazol-1-yl)ethane
    Yuping Zhang
    Liyan Wang
    Shouwu Wang
    Baolong Li
    Yong Zhang
    Journal of Chemical Crystallography, 2008, 38 : 81 - 84
  • [4] Synthesis and crystal structure of a one-dimensional chain cadmium coordination polymer bridged through 1,2-bis(imidazol-1-yl)ethane
    Zhang, Yuping
    Wang, Liyan
    Wang, Shouwu
    Li, Baolong
    Zhang, Yong
    JOURNAL OF CHEMICAL CRYSTALLOGRAPHY, 2008, 38 (02) : 81 - 84
  • [5] 1,2-Bis[4-(1H-imidazol-1-yl)benzy-lidene]hydrazine
    Jin, Yue-Bao
    Li, Jie
    Zhang, Ying
    Lei, Ke-Wei
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2012, 68 : O1949 - +
  • [6] (1E, 2E)-1,2-Bis[(1-benzyloxymethyl-1H-indol-3-yl) methylidene] hydrazine
    Myers, Jacob A.
    Fronczek, Frank R.
    Watkins, Steven F.
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2012, 68 : O3158 - +
  • [7] Bis[μ-2-(1H-imidazol-2-yl)phenolato]-bis[chloromethanolcopper(II)]
    He, Hong-Shan
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2006, 62 : M1782 - M1783
  • [8] 1,2-bis[2-(2-nitro-1H-imidazol-1-yl)ethoxy]ethane
    Li, Shu-Xian
    Zhu, Lin
    Li, Hua-Min
    Fun, Hoong-Kun
    Chantrapromma, Suchada
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2008, 64 : O1690 - U1344
  • [9] TDDFT investigation on electronically excited-state hydrogen-bonding properties and ESIPT mechanism for the 2-(1H-imidazol-2-yl)-phenol compound
    Yang, Guang
    Chen, Kaifeng
    Wang, Gang
    Yang, Dapeng
    STRUCTURAL CHEMISTRY, 2021, 32 (03) : 997 - 1003
  • [10] TDDFT investigation on electronically excited-state hydrogen-bonding properties and ESIPT mechanism for the 2-(1H-imidazol-2-yl)-phenol compound
    Guang Yang
    Kaifeng Chen
    Gang Wang
    Dapeng Yang
    Structural Chemistry, 2021, 32 : 997 - 1003